Polybiphenylmethylenes: New Polymers for Bistable Organic Switches
نویسندگان
چکیده
Introduction Advances in microelectronic materials and processing techniques have pushed device sizes much smaller than micrometer dimensions. Hence, the new realm of electronic devices can be more accurately described as nanoelectronics. Phenomenon in thin film organic materials is now being used to create operational devices with active elements approaching single molecule dimensions. We have recently disclosed thin layer organic device architectures that can be used to fabricate high density storage elements – so called organic electronically bistable devices. There is currently a search for polymeric materials with fine-tuned properties to enhance operation of these devices. Additionally, we also investigate conjugated polymers where applied as semiconductors or for electroluminescent devices. With various transition metal catalyzed step-growth polymerization techniques in hand many, usually semiconducting, phenyl group containing polymers like PPPs, Polyfluorenes (Suzuki, Yamamoto) and PPEs (Sonogashira) have been synthesized in the past decade. Monomers with aromatic bromides were utilized in most cases, less often aryl iodides, chlorides and sulfonates. Polymers with Mn = 10.000 g/mol are mainly yielded, which is sufficient for most applications. We desired to explore a new class of polymeric materials containing a high content of aromatic units, specifically with short conjugated segments bridged by non-conjugated methylene units. Herein we report on the synthesis and characterization of poly(biphenylmethylene)s and their corresponding monomers. We also report the preliminary results of their electronic device characterization.
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تاریخ انتشار 2004