Polybiphenylmethylenes: New Polymers for Bistable Organic Switches

نویسندگان

  • Matthias Beinhoff
  • Luisa D. Bozano
چکیده

Introduction Advances in microelectronic materials and processing techniques have pushed device sizes much smaller than micrometer dimensions. Hence, the new realm of electronic devices can be more accurately described as nanoelectronics. Phenomenon in thin film organic materials is now being used to create operational devices with active elements approaching single molecule dimensions. We have recently disclosed thin layer organic device architectures that can be used to fabricate high density storage elements – so called organic electronically bistable devices. There is currently a search for polymeric materials with fine-tuned properties to enhance operation of these devices. Additionally, we also investigate conjugated polymers where applied as semiconductors or for electroluminescent devices. With various transition metal catalyzed step-growth polymerization techniques in hand many, usually semiconducting, phenyl group containing polymers like PPPs, Polyfluorenes (Suzuki, Yamamoto) and PPEs (Sonogashira) have been synthesized in the past decade. Monomers with aromatic bromides were utilized in most cases, less often aryl iodides, chlorides and sulfonates. Polymers with Mn = 10.000 g/mol are mainly yielded, which is sufficient for most applications. We desired to explore a new class of polymeric materials containing a high content of aromatic units, specifically with short conjugated segments bridged by non-conjugated methylene units. Herein we report on the synthesis and characterization of poly(biphenylmethylene)s and their corresponding monomers. We also report the preliminary results of their electronic device characterization.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Isoindolinone-based molecular switches.

Switches are frequently used to provide external control over the conformation and function of organic and bio-organic molecules. While the use of bistable switches is widespread, multi-stable examples are observed relatively rarely. Reported here is a new class of molecular switch that is capable of forming three stable states of varied geometries, two of which can be induced to interconvert r...

متن کامل

On the functional relevance of frontal cortex for passive and voluntarily controlled bistable vision.

In bistable vision, one constant ambiguous stimulus leads to 2 alternating conscious percepts. This perceptual switching occurs spontaneously but can also be influenced through voluntary control. Neuroimaging studies have reported that frontal regions are activated during spontaneous perceptual switches, leading some researchers to suggest that frontal regions causally induce perceptual switche...

متن کامل

Memory Switches in Chemical Reaction Space

Just as complex electronic circuits are built from simple Boolean gates, diverse biological functions, including signal transduction, differentiation, and stress response, frequently use biochemical switches as a functional module. A relatively small number of such switches have been described in the literature, and these exhibit considerable diversity in chemical topology. We asked if biochemi...

متن کامل

New organic bistable ®lms for ultrafast electric memories

Thin ®lms which have electrical bistable effects are mostly metal-organic complexes and/or organic-organic (all-organic) complexes. Very recently some simple (mono-molecular) organic materials have been discovered which have bistable states at room temperature, too. The threshold voltage across these organic ®lms with a thickness of 60 nm is 4±6 V and the transition time is 5±10 ns. Therefore, ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2004